姓名:于凯
职务职称:教授、博士生导师
研究领域:固废物资源化(废高分子、冶金固废、电子废弃物)、环境催化(生物质催化转化、光催化)
联系电话:022-85358635
邮箱:kaiyu@nankai.edu.cn
教育背景
2002.9~2005.7,南开大学化学学院,物理化学专业,理学硕士。
1998.9~2002.7,南开大学化学学院,化学专业,理学学士。
科研教学经历
2019.12至今,beat365官方网站,教授。
2016.12~2017.12,英国圣安德鲁斯大学化学系,访问学者。
2010.12~2019.12,beat365官方网站,副教授。
2008.7~2010.12,beat365官方网站,讲师。
主讲课程
《无机及分析化学》(2022至今)本科生必修课;
《资源循环利用综合实验(二)》(2020至今)本科生必修课;
《现代仪器分析技术》(2013至今)本科生选修课;
《固体废弃物资源综合利用技术》(2018至今)研究生必修课。
学术与社会任职
天津市废轮胎铺面材料工程技术中心副主任、天津市钢铁及冶金制品清洁技术工程中心副主任、中国再生资源产业技术创新战略联盟专家委员、《石油学报(石油加工)》(EI)青年编委。
科研项目
国家重点研发计划“钢铁尘泥与有机固废低碳协同利用技术及装备”项目课题:“含铁锌多金属尘泥碳氢耦合深度还原技术(2022YFC3901401,2022.11~2025.12,354万元)”;(主持,在研)
天津市碳达峰碳中和科技重大专项项目:“钢铁烧结工序节能降碳与减排增效关键技术与示范(21ZXCCSN00010,2022.01~2024.14,200万元)”;(主持,在研)
国家自然科学基金面上项目:“金属-氧化物界面氧空位在生物质醇醛液相氧化反应中的构效关系研究(22172081,2022.01~2025.12,76.8万元)”;(主持,在研)
国家自然科学基金联合基金项目:“面向2,5-呋喃二甲酸高效合成的非贵金属催化研究(U23A20125,2024.01~2027.12,260万元)”(参与,在研)
校企平台合作项目:“南开大学-新越股份绿色低碳道路新材料联合研发中心项目(2022.01~2024.12,300万元)”;(主持,在研)
国家863计划项目课题:“废轮胎胶粉改性利用关键技术(2012AA063008,2012.01~2014.12,540万元)”;(课题技术负责人,已结题)
天津市应用基础及前沿技术研究计划一般项目:“废轮胎胶粉的接枝改性对胶粉改性沥青界面相容性的影响和调控机理研究(17JCYBJC22600,2017.04~2020.03,10万元)”;(主持,已结题)
天津市科技特派员项目:“废轮胎胶粉的表面聚合接枝改性及其在改性沥青中的应用研究(15JCTPJC63500,2015.10~2016.09,5万元)”;(主持,已结题)
天津市科技支撑计划重点项目:“再生资源固废物复合改性道路沥青技术(07ZCGYSH02000,2007.04~2009.09,75万元)”;(骨干参与,已结题)
高等学校博士学科点专项科研基金项目:“纳米孔道精细调控制备高效烯烃不对称环氧化催化剂(20100031120029,2011.01~2013.12,3.6万元)”;(主持,已结题)
中央高校基本科研业务费:“再生橡胶中多环芳烃的光催化降解研究(2010.06~2012.05,15万元)”;(主持,已结题)
企业委托课题:“废轮胎胶粉改性沥青技术开发(2019.03~2021.03,15万元)”;(主持,已结题)
企业委托课题:“HT-16改性剂的多组份分离及成份分析技术(2016.11~2017.06,10万元)”;(主持,已结题)
企业委托课题:“轮胎热裂解产业发展及轮胎热裂解发电技术可行性研究”;(主持,已结题)
企业委托课题:“废旧轮胎资源综合利用技术的低碳分析”;(主持,已结题)
学术论著
近年代表性论文:
u Weiping Yang, Fuyuan Qi, Wenjing An, Haochen Yu, Shutong Liu, Peipei Ma, Rui Chen, Shuangxi Liu, Lan-Lan Lou*, Kai Yu*. Local electronic structure modulation of interfacial oxygen vacancies promotes oxygen activation capacity of Pt/Ce1-xMxO2-δ. ACS Catalysis (2024) just accepted.
u Meiyang Wang, Zhenzong Zhang, Zexu Chi, Lan-lan Lou, Hui Li, Han Yu*, Tianyi Ma*, Kai Yu*, Hao Wang. Alkali metal cations as charge-transfer bridge for polarization promoted solar-to-H2 conversion. Advanced Functional Materials 33 (2023) 2211565.
u Meiyang Wang, Han Yu*, Kai Yu*. Advances in bismuth-based non-centrosymmetric materials aspolarization-enhanced photocatalysts for environmental remediation and energy conversion. Chemical Engineering Journal 470 (2023) 144100.
u Beibei Wang, Kejiang Qian, Weiping Yang, Wenjing An, Lan-Lan Lou*, Shuangxi Liu, Kai Yu*. ZnFe2O4/BiVO4 Z-scheme heterojunction for efficient visible-light photocatalytic degradation of ciprofloxacin. Frontiers of Chemical Science and Engineering 17 (2023) 1728−1740.
u Weiping Yang, Haochen Yu, Beibei Wang, Xuemin Wang, Hao Zhang, Da Lei, Lan-Lan Lou,* Kai Yu,* Shuangxi Liu. Leveraging Pt/Ce1−xLaxO2−δ to elucidate interfacial oxygen vacancy active sites for aerobic oxidation of 5‑hydroxymethylfurfural. ACS Applied Material & Interfaces 14 (2022) 37667−37680.
u Fuyuan Qi, Weiping Yang, Haochen Yu, Lan-Lan Lou*, Shuangxi Liu, Kai Yu*. Manipulating interfacial atomic structure of Pt/Ce1-xYxO2-δ to improve charge transfer capacity and catalytic activity in aerobic oxidation of HMF. Applied Surface Science 598 (2022) 153769.
u Huiying Quan, Kejiang Qian, Ying Xuan, Lan-Lan Lou, Kai Yu*, Shuangxi Liu. Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO3 decorated with ZnxCd1–xS. Frontiers of Chemical Science and Engineering 15 (2021) 1561−1571.
u Kai Yu, Lan-Lan Lou*, Shuangxi Liu, Wuzong Zhou*. Asymmetric oxygen vacancies: The intrinsic redox active sites in metal oxide catalysts. Advanced Science 7 (2020) 1901970.
u Yue Chang, Ying Xuan, Huiying Quan, Hang Zhang, Shuangxi Liu, Zhengcao Li, Kai Yu*, Jiangli Cao*. Hydrogen treated Au/3DOM-TiO2 with promoted photocatalytic efficiency for hydrogen evolution from water splitting, Chemical Engineering Journal, 382 (2020) 122869.
u Ying Xuan, Huiying Quan, Zhurui Shen,* Chenxi Zhang, Xiyuan Yang, Lan-Lan Lou, Shuangxi Liu, Kai Yu*. Band‐gap and charge transfer engineering in red phosphorus based composite for enhanced visible‐light‐driven H2 evolution. Chemistry-A European Journal, 26 (2020) 2285-2292.
u Yaqi Liu, Hong-Yan Ma, Da Lei, Lan-Lan Lou, Shuangxi Liu, Wuzong Zhou, Gui-Chang Wang*, Kai Yu*. Active oxygen species promoted catalytic oxidation of 5‑hydroxymethyl-2-furfural on facet-specific Pt nanocrystals. ACS Catalysis 9 (2019) 8306−8315.
u Chenxi Zhang, Peiyuan Zhao, Shuangxi Liu,Kai Yu*. Three-dimensionally ordered macroporous perovskite materials for environmental applications. Chinese Journal of Catalysis 40 (2019) 1324–1338.
u Jie Yang, Haochen Yu, Yanbing Wang, Haodong Liu, Fuyuan Qi, Lan-Lan Lou, Kai Yu*, Wuzong Zhou, Shuangxi Liu. Effect of oxygen coordination environment of Ca-Mn oxides on catalytic performance of Pd supported catalysts for aerobic oxidation of 5-hydroxymethyl-2-furfural. Catalysis Science & Technology 9 (2019) 6659−6668.
u Yue Chang, Ying Xuan, Chenxi Zhang, He Hao, Kai Yu*, Shuangxi Liu. Z-Scheme Pt@CdS/3DOM-SrTiO3 composite with enhanced photocatalytic hydrogen evolution from water splitting. Catalysis Today 327 (2019) 315–322.
u Kai Yu, Da Lei, Yajun Feng, Haochen Yu, Yue Chang, Yanbing Wang, Yaqi Liu, Gui-Chang Wang, Lan-Lan Lou*, Shuangxi Liu*, Wuzong Zhou*. The role of Bi-doping in promoting electron transfer and catalytic performance of Pt/3DOM-Ce1-xBixO2-δ. Journal of Catalysis 365(2018) 292–302.
u Kai Yu*, Yaqi Liu, Da Lei, Yuanzhi Jiang, Yanbing Wang, Yajun Feng, Lan-Lan Lou, Shuangxi Liu*, Wuzong Zhou*. M3+O(–Mn4+)2 clusters in doped MnOx catalysts as promoted active sites for the aerobic oxidation of 5-hydroxymethylfurfural. Catalysis Science & Technology 8 (2018) 2299-2303.
u Da Lei,Kai Yu*, Meng-Ru Li, Yuling Wang, Qi Wang, Tong Liu, Pengkun Liu, Lan-Lan Lou, Guichang Wang*, Shuangxi Liu*. Facet effect of single-crystalline Pd nanocrystals for aerobic oxidation of 5-hydroxymethyl-2-furfural. ACS Catalysis 7 (2017) 421-432.
u Yue Chang, Kai Yu*, Chenxi Zhang, Zequn Yang, Yajun Feng, He Hao, Yuanzhi Jiang, Lan-Lan Lou, Wuzong Zhou, Shuangxi Liu*. Ternary CdS/Au/3DOM-SrTiO3 composites with synergistic enhancement for hydrogen production from visible-light photocatalytic water splitting. Applied Catalysis B: Environmental, 15 (2017) 74-84.
u Chenxi Zhang,Kai Yu*, Yajun Feng, Yue Chang, Ting Yang, Ying Xuan, Da Lei, Lan-Lan Lou, Shuangxi Liu*. Novel 3DOM-SrTiO3/Ag/Ag3PO4 ternary Z-scheme photocatalysts with remarkably improved activity and durability for contaminant degradation. Applied Catalysis B: Environmental, 210 (2017) 77-87.
u Kai Yu*, Chenxi Zhang, Yue Chang, Yajun Feng, Zequn Yang, Ting Yang, Lan-Lan Lou, Shuangxi Liu*. Novel three-dimensionally ordered macroporous SrTiO3 photocatalysts with remarkably enhanced hydrogen production performance. Applied Catalysis B: Environmental, 200 (2017) 514-520.
u Yanbing Wang, Kai Yu*, Da Lei, Wei Si, Yajun Feng, Lan-Lan Lou, Shuangxi Liu*. Basicity-tuned hydrotalcite supported Pd catalysts for aerobic oxidation of 5-hydroxymethyl-2-furfural under mild conditions. ACS Sustainable Chemistry & Engineering, 4 (2016) 4752-4761.
u Yue Chang, Kai Yu*, Chenxi Zhang, Rui Li, Peiyuan Zhao, Lan-Lan Lou, Shuangxi Liu*. Three-dimensionally ordered macroporous WO3 supported Ag3PO4 with enhanced photocatalytic activity and durability. Applied Catalysis B: Environmental, 176 (2015) 363-373.
u 张寅清, 张琛, 李翠红, 李彤彤, 张楠, 汪锦, 于凯*, 刘双喜. 聚苯乙烯接枝胶粉对改性沥青性能的影响. 环境工程学报, 14 (2020) 490-497.
u 于凯, 张琛, 王欢, 张楠, 陆宇鹏, 李彤彤, 李沁宇, 刘双喜*. 次氯酸钠氧化废轮胎胶粉对改性沥青性能的影响研究. 环境工程学报, 10 (2016) 350-354.
u 于凯, 王欢, 韩赫兴, 李瑞, 陈小玉, 杜鹃, 权伟, 刘双喜*. 双氧水氧化废轮胎胶粉在改性沥青中的应用. 天津大学学报(自然科学与工程技术版), 47 (2014) 949-954.
u 于凯, 刘力, 余强, 朱坦, 刘双喜*. 废轮胎胶粉和废PE复合改性沥青性能研究. 环境工程学报, 4 (2010) 689-692.
授权发明专利:
u 于凯, 杨蔚萍, 王贝贝, 楼兰兰. 铈镧复合氧化物载体的制备方法及其负载铂的催化剂与应用. ZL 202210517051.6
u 于凯, 王欢, 刘双喜, 陈小玉, 韩赫兴, 李瑞, 权伟, 杜鹃. 一种沥青改性用废轮胎胶粉的表面氧化改性工艺. ZL 201310079851.5
u 刘双喜, 于凯, 董艳玲. 一种废轮胎胶粉中多环芳烃的降解方法. ZL 201110009171.7
荣誉与奖励
“道路材料主动净味技术开发”获得2020年天津市环境保护科学技术奖三等奖;
“节能环保废轮胎胶粉改性沥青路面新材料技术”获得2015年天津市科学技术进步奖二等奖;
2015年天津市优秀科技特派员。